ICARUS Chamber Experiment: Nguyen Group_20191125_ALPHA-PINENE/OZONE/10102-44-0/hydrogen peroxide_Nitrate radical_SOA

d789687
| DOI: 10.5065/2504-RZ79
 
Abstract:

Goals:
To quantify the nitrooxy-hydroperoxide yield and the SOA yield from nighttime RO2+HO2-dominated NO3-initiated chemistry of a-pinene by adding H2O2 + ozone + NO2 to the chamber. Part of a series of varying initial reactant concentrations slightly to target different chemical pathways. This one differs from the others in its use of organic seed aerosol rather than ammonium sulfate

Summary:
H2O2, NO2, and O3 were injected in the chamber and allowed to equilibrate, forming NO3 (and some N2O5) and probably HO2. Organic seed particles were injected. Then a-pinene was injected and decayed by simultaneous reaction with ozone and NO3. Gas phase was monitored by CF3O- CIMS and particle formation by SMPS.

Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Nitrate radical
Reactants: ALPHA-PINENE, OZONE, 10102-44-0, hydrogen peroxide
Reaction Type: Dark oxidation
Relative Humidity: 5
Temperature: 22
Seed Name: SOA
Pressure: 755 Torr

Temporal Range:
2019-11-25 to 2019-11-25
Variables:
Trace Gases/Trace Species
Data Types:
Platform Observation
Data Contributors:
UC-DAVIS/CHEMISTRY
Department of Chemistry, University of California, Davis
Related Resources:
Total Volume:
0.05 MB
Data Formats:
ASCII (see dataset documentation)
Metadata Record:
Data License:
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