Aug 23, 2023

ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20140812_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_No Seed_Dry

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Version: 20230823-020148

Goals:
This experiment was done to react Methacrolein (MACR) with OH in the high NO2 condition observe the true SOA formation yield. This is to compare its oxidation with pure MPAN, which comes from MACR. This experiment was done with Methyl Nitrite (CH3ONO) as the OH precursor at 15 celsius.

Summary:
The reaction produced a lot of SOA through dry nucleation.

Organization: Caltech Atmospheric Chamber
Lab Affiliation: California Institute of Technology, Pasadena, CA
Chamber: Near/Far Bag 2012-2015 (Tran)

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Hydroxyl radical
Reactants: METHACROLEIN, Methyl nitrite, 10102-44-0
Reaction Type: Photooxidation
Relative Humidity: 4
Temperature: 15
Pressure: 750 Torr

DOI: https://doi.org/10.5065/5vey-7492

ICARUS Experiment Details: https://icarus.ucdavis.edu/experiment/617

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Temporal Range: 2014-08-12 to 2014-08-12

Related Links: Publication - Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere

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GCMD Instruments

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Support Contact

Kong, Stephanie
Caltech Atmospheric Chamber
wkong@caltech.edu

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints: Creative Commons Attribution 4.0 International License.

Access Constraints: These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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Authors: Seinfeld, John

Publisher

ICARUS Community

Suggested Citation: Seinfeld, John. (2023). ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20140812_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_No Seed_Dry. Version 20230823-020148. ICARUS Community. https://doi.org/10.5065/5vey-7492. Accessed 10 Jan 2025.

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