Aug 23, 2023

ICARUS Chamber Experiment: Nguyen Group_20210322_ALPHA-PINENE/OZONE/hydrogen peroxide_Ozone_N/A


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Version: 20230823-020108

Goals:
To quantify the nitrooxy-hydroperoxide yield and the SOA yield from nighttime RO2+HO2-dominated NO3-initiated chemistry of a-pinene by adding H2O2 + ozone + NO2 to the chamber. This experiment was predominantly to collect a filter to analyze the chemical content of pinene ozonolysis SOA by offline HRMS.

Summary:
H2O2 and O3 were injected in the chamber and allowed to equilibrate. Then a-pinene was injected and decayed by reaction with ozone. The first pinene injection (100 ppb) didn't produce enough SOA for a good filter to analyze by HRMS, so more pinene was injected (150 ppb) over two periods until SOA produced was >200 ug/m3. Gas phase was monitored by CF3O- CIMS and particle formation by SMPS. After all injections, a filter was collected for offline HRMS analysis.

Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Ozone
Reactants: ALPHA-PINENE, OZONE, hydrogen peroxide
Reaction Type: Dark oxidation
Relative Humidity: 5
Temperature: 22
Seed Name: N/A
Pressure: 755 Torr

DOI
https://doi.org/10.5065/my7e-2b85
ICARUS Experiment Details
https://icarus.ucdavis.edu/experiment/589
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Temporal Range
2021-03-22 to 2021-03-22
Related Links
N/A
GCMD Science Keywords
  • Atmosphere > Aerosols
  • Atmosphere > Atmospheric Chemistry > Trace Gases/Trace Species
GCMD Instruments
  • In Situ/Laboratory Instruments > Chemical Meters/Analyzers
File Media Types
  • application/zip
Support Contact
Bates, Kelvin
Nguyen Group
kelvinhbates@gmail.com

Data Curator
GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints
Creative Commons Attribution 4.0 International License.
Access Constraints
These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.
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Authors
Nguyen, Tran
Publisher
ICARUS Community

Suggested Citation
Nguyen, Tran. (2023). ICARUS Chamber Experiment: Nguyen Group_20210322_ALPHA-PINENE/OZONE/hydrogen peroxide_Ozone_N/A. Version 20230823-020108. ICARUS Community. https://doi.org/10.5065/my7e-2b85. Accessed 08 Nov 2024.
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