Aug 23, 2023

ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180202_DECANE/nitric oxide/nitrite_Chlorine radical_Ammonium sulfate_med RH

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Version: 20230823-015216

Goals:
Find SOA yield for decane + Cl under high NOx condition (NO and NO2 injected) at RH=40%. Investigate volatility behavior based on 2D thermograms.

Summary:
Ammonium sulfate seed (0.01M, 150 mL) was injected using an aerosol generation system. Cl2 gas, NO and NO2 gas were injected from their cylinders. 81 ug/m3 of decane was injected into a glass bulb and heated clean air was made to flow over it, carrying the volatilized decane into the chamber. After ~30 mins (sufficient mixing time), lights were turned on for 1 hour. 40.7 ug/m3 of SOA was formed, giving a mass yield of 0.50. This is Exp#8 in associated publication.

Organization: Hildebrandt Ruiz Lab
Lab Affiliation: University of Texas at Austin, Austin, TX, USA
Chamber: LHR Chamber

Experiment Category: Gas phase chemical reaction, Volatility and partitioning, Aerosol formation
Oxidant: Chlorine radical
Reactants: DECANE, nitric oxide, nitrite
Reaction Type: Photooxidation
Relative Humidity: 40
Temperature: 25
Seed Name: Ammonium sulfate

DOI: https://doi.org/10.5065/erh9-8x04

ICARUS Experiment Details: https://icarus.ucdavis.edu/experiment/220

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Temporal Range: 2018-02-02 to 2018-02-02

Related Links: Publication - Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO?CIMS

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Support Contact

Hildebrandt Ruiz, Lea
Hildebrandt Ruiz Lab
lhr@che.utexas.edu

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints: Creative Commons Attribution 4.0 International License.

Access Constraints: These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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Authors: Hildebrandt Ruiz, Lea

Publisher

ICARUS Community

Suggested Citation: Hildebrandt Ruiz, Lea. (2023). ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180202_DECANE/nitric oxide/nitrite_Chlorine radical_Ammonium sulfate_med RH. Version 20230823-015216. ICARUS Community. https://doi.org/10.5065/erh9-8x04. Accessed 11 Jan 2025.

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