Goals:
Find SOA yield for octane + Cl under high NOx condition (NO injected). Investigate volatility behavior based on 2D thermograms.
Summary:
Ammonium sulfate seed (0.01M, 150 mL) was injected using an aerosol generation system. Cl2 gas and NO gas were injected from their cylinders. 1 uL of octane was injected into a glass bulb and heated clean air was made to flow over it, carrying the volatilized octane into the chamber. After ~30 mins (sufficient mixing time), lights were turned on for 1 hour (12:27:50-13:27:50). At 13:35, a FIGAERO collection began for 45 mins, followed by a desorption. A second FIGAERO collection began at 3:44 PM.
Organization: Hildebrandt Ruiz Lab
Lab Affiliation: University of Texas at Austin, Austin, TX, USA
Chamber: LHR Chamber
Experiment Category: Gas phase chemical reaction, Volatility and partitioning, Aerosol formation
Oxidant: Chlorine radical
Reactants: octane, nitric oxide
Reaction Type: Photooxidation
Temperature: 25
Seed Name: Ammonium sulfate
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