Aug 23, 2023

ICARUS Chamber Experiment: Nguyen Group_20210204_2-methylbut-3-ene-1,2-diol/Methyl nitrite_Hydroxyl radical_Ammonium sulfate


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Version: 20230823-015904

Goals:
Product & SOA formation study on 2-methylbut-3-ene-1,2-diol (1,2-DHI) + OH, seeded (ammonium sulfate), dry, trying to get the best conditions possible for any isomerization/autooxidation to occur (including high temperature, low OH / light)

Summary:
The chamber was heated to 35?C and all but two lights were removed from the chamber (~3% of max light flux). 1,2-DHI and CH3ONO were injected, AS was atomized, and the bag was allowed to mix and equilibrate, after which the lights were turned on and left on overnight (>24 h). The CIMS was ran out of reagent gas, so signals were pretty wonky after 6:00am on the second day.

Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air

Experiment Category: Gas phase chemical reaction
Oxidant: Hydroxyl radical
Reactants: 2-methylbut-3-ene-1,2-diol, Methyl nitrite
Reaction Type: Photooxidation
Relative Humidity: 5
Temperature: 35
Seed Name: Ammonium sulfate
Pressure: 755

DOI
https://doi.org/10.5065/9rb1-pn14
ICARUS Experiment Details
https://icarus.ucdavis.edu/experiment/544
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Temporal Range
2021-02-04 to 2021-02-04
Related Links
Publication - Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene
GCMD Science Keywords
  • Atmosphere > Aerosols
  • Atmosphere > Atmospheric Chemistry > Trace Gases/Trace Species
GCMD Instruments
  • In Situ/Laboratory Instruments > Chemical Meters/Analyzers
File Media Types
  • application/zip
Support Contact
Bates, Kelvin
Nguyen Group
kelvinhbates@gmail.com

Data Curator
GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints
Creative Commons Attribution 4.0 International License.
Access Constraints
These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.
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Authors
Nguyen, Tran
Publisher
ICARUS Community

Suggested Citation
Nguyen, Tran. (2023). ICARUS Chamber Experiment: Nguyen Group_20210204_2-methylbut-3-ene-1,2-diol/Methyl nitrite_Hydroxyl radical_Ammonium sulfate. Version 20230823-015904. ICARUS Community. https://doi.org/10.5065/9rb1-pn14. Accessed 17 Jun 2025.
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