ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180117_DODECANE/nitric oxide/nitrite_Chlorine radical_Ammonium sulfate_high RH
Goals:
Find SOA yield for dodecane + Cl under high NOx condition (NO and NO2 injected) at RH=67%. Investigate volatility behavior based on 2D thermograms.
Summary:
Ammonium sulfate seed (0.01M, 150 mL) was injected using an aerosol generation system. Cl2 gas, NO and NO2 gas were injected from their cylinders. 90 ug/m3 of dodecane was injected into a glass bulb and heated clean air was made to flow over it, carrying the volatilized dodecane into the chamber. After ~30 mins (sufficient mixing time), lights were turned on for 1 hour. 98.9 ug/m3 of SOA was formed, giving a mass yield of 1.10. This is Exp#12 in associated publication.
Organization: Hildebrandt Ruiz Lab
Lab Affiliation: University of Texas at Austin, Austin, TX, USA
Chamber: LHR Chamber
Experiment Category: Gas phase chemical reaction, Volatility and partitioning, Aerosol formation
Oxidant: Chlorine radical
Reactants: DODECANE, nitric oxide, nitrite
Reaction Type: Photooxidation
Relative Humidity: 67
Temperature: 25
Seed Name: Ammonium sulfate
- ICARUS Experiment Details
- https://icarus.ucdavis.edu/experiment/225
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- Temporal Range
- 2018-01-17 to 2018-01-17
- Related Links
- Publication - Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO?CIMS
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- GCMD Instruments
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Hildebrandt Ruiz Lab
lhr@che.utexas.edu
UCAR/NCAR - GDEX
gdex@ucar.edu
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- Authors
- Hildebrandt Ruiz, Lea
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