Goals:
Control experiment for the O3+NO2+H2O2 series -- this one with no H2O2, and therefore likely very little HO2 formation during oxidation (more RO2 + RO2, some RO2 + NO3 likely)
Summary:
NO2 and O3 were injected in the chamber and allowed to equilibrate, forming NO3 (and some N2O5). Ammonium sulfate seed particles were injected. Then a-pinene was injected and decayed by simultaneous reaction with ozone and NO3. Gas phase was monitored by CF3O- CIMS and particle formation by SMPS. A filter was collected for later offline analysis.
Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air
Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Nitrate radical
Reactants: ALPHA-PINENE, OZONE, 10102-44-0
Reaction Type: Dark oxidation
Relative Humidity: 5
Temperature: 22
Seed Name: Ammonium sulfate
Pressure: 755 Torr
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