Aug 23, 2023

ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180103_DODECANE/nitrite_Chlorine radical_Ammonium sulfate_dry


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Version: 20230823-015216

Goals:
Find SOA yield for dodecane + Cl under high NOx condition (NO2 injected). Investigate volatility behavior based on 2D thermograms.

Summary:
Ammonium sulfate seed (0.01M, 150 mL) was injected using an aerosol generation system. Cl2 gas and NO2 gas were injected from their cylinders. 90 ug/m3 of dodecane was injected into a glass bulb and heated clean air was made to flow over it, carrying the volatilized dodecane into the chamber. After ~30 mins (sufficient mixing time), lights were turned on for 1 hour. 112.8 ug/m3 of SOA was formed, giving a mass yield of 1.25. This is Exp#10 in associated publication.

Organization: Hildebrandt Ruiz Lab
Lab Affiliation: University of Texas at Austin, Austin, TX, USA
Chamber: LHR Chamber

Experiment Category: Gas phase chemical reaction, Volatility and partitioning, Aerosol formation
Oxidant: Chlorine radical
Reactants: DODECANE, nitrite
Reaction Type: Photooxidation
Temperature: 25
Seed Name: Ammonium sulfate

DOI
https://doi.org/10.5065/xrcg-fb12
ICARUS Experiment Details
https://icarus.ucdavis.edu/experiment/222
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1 Files, 371.72 KB Total Size

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Temporal Range
2018-01-03 to 2018-01-03
Related Links
Publication - Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO?CIMS
GCMD Science Keywords
  • Atmosphere > Aerosols
  • Atmosphere > Atmospheric Chemistry > Trace Gases/Trace Species
GCMD Instruments
  • In Situ/Laboratory Instruments > Chemical Meters/Analyzers
File Media Types
  • application/zip
Support Contact
Hildebrandt Ruiz, Lea
Hildebrandt Ruiz Lab
lhr@che.utexas.edu

Data Curator
GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints
Creative Commons Attribution 4.0 International License.
Access Constraints
These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.
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Authors
Hildebrandt Ruiz, Lea
Publisher
ICARUS Community

Suggested Citation
Hildebrandt Ruiz, Lea. (2023). ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180103_DODECANE/nitrite_Chlorine radical_Ammonium sulfate_dry. Version 20230823-015216. ICARUS Community. https://doi.org/10.5065/xrcg-fb12. Accessed 11 Jan 2025.
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