Aug 23, 2023

ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20131116_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH44

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Version: 20230823-020209

Goals:
This experiment was performed to study product formation from stabilized Criegee intermediates (SCI) in the Isoprene + ozone under various relative humidity (RH) conditions with cyclohexane as an OH scavenger. This investigates the reaction of the simplest SCI (CH2OO) with water and water dimer

Summary:
Significant amounts of CH2OO + H2O products (HMHP, formic acid, and H2O2) were observed

Organization: Caltech Atmospheric Chamber
Lab Affiliation: California Institute of Technology, Pasadena, CA
Chamber: Near/Far Bag 2012-2015 (Tran)

Experiment Category: Gas phase chemical reaction
Oxidant: Ozone
Reactants: ISOPRENE, CYCLOHEXANE
Reaction Type: Dark oxidation
Relative Humidity: 44
Temperature: 24
Pressure: 750 Torr

DOI: https://doi.org/10.5065/h3ky-qh67

ICARUS Experiment Details: https://icarus.ucdavis.edu/experiment/635

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Temporal Range: 2013-11-16 to 2013-11-16

Related Links: Publication - Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene

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Support Contact

Kong, Stephanie
Caltech Atmospheric Chamber
wkong@caltech.edu

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints: Creative Commons Attribution 4.0 International License.

Access Constraints: These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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Authors: Seinfeld, John

Publisher

ICARUS Community

Suggested Citation: Seinfeld, John. (2023). ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20131116_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH44. Version 20230823-020209. ICARUS Community. https://doi.org/10.5065/h3ky-qh67. Accessed 11 Jan 2025.

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