Aug 22, 2023

ICARUS Chamber Experiment: Ziemann_20170827_pyrocatechol/nitric oxide/Methyl nitrite_Hydroxyl radical_Dioctyl Sebacate_Catechol + OH/NOx_highNO

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Version: 20230822-015118

Goals:
Determine the SOA yield, products and molar yield of SOA products for the reaction of catechol with OH in the presence of NOx at a different NO:NO2 ratio to see how that impacts 4NC yield.

Summary:
Reaction occurred in 5 minutes, was conducted at 50% lights, reacting 29 ppb of catechol. SOA mass yield was 138%, 4-nitrocatechol yield was 27%.

Organization: Ziemann
Lab Affiliation: University of Colorado, Boulder, Boulder, CO, USA
Chamber: Janet (Chamber 1)

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Hydroxyl radical
Reactants: pyrocatechol, nitric oxide, Methyl nitrite
Reaction Type: Photooxidation
Relative Humidity: 1
Temperature: 23
Seed Name: Dioctyl Sebacate
Pressure: 630 Torr

DOI: https://doi.org/10.5065/0e04-ey92

ICARUS Experiment Details: https://icarus.ucdavis.edu/experiment/162

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Temporal Range: 2017-08-27 to 2017-08-27

Related Links: Publication - Identification and Quantification of 4?Nitrocatechol Formed from OH and NO3 Radical-Initiated Reactions of Catechol in Air in the Presence of NOx: Implications for Secondary Organic Aerosol Formation from Biomass Burning

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Support Contact

DeVault, Marla
Ziemann
marla.devault@colorado.edu

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints: Creative Commons Attribution 4.0 International License.

Access Constraints: These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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Authors: Ziemann, Paul

Publisher

ICARUS Community

Suggested Citation: Ziemann, Paul. (2023). ICARUS Chamber Experiment: Ziemann_20170827_pyrocatechol/nitric oxide/Methyl nitrite_Hydroxyl radical_Dioctyl Sebacate_Catechol + OH/NOx_highNO. Version 20230822-015118. ICARUS Community. https://doi.org/10.5065/0e04-ey92. Accessed 08 Jan 2025.

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