Goals:
To assess the feasibility of accessing nighttime HO2-dominated chemistry of a-pinene by adding H2O2 + ozone + NO2 to the chamber. Overall goals will include quantifying the nitrooxy-hydroperoxide yield and the SOA yield from this reaction pathway
Summary:
H2O2, NO2, and O3 were injected in the chamber and allowed to equilibrate, forming NO3 (and some N2O5) and probably HO2. Then a-pinene was injected and decayed by simultaneous reaction with ozone and NO3. Gas phase was monitored by CF3O- CIMS and particle formation by SMPS. A filter was collected for later offline analysis.
Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air
Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Nitrate radical
Reactants: ALPHA-PINENE, hydrogen peroxide, OZONE, 10102-44-0
Reaction Type: Dark oxidation
Relative Humidity: 5
Temperature: 22
Seed Name: Ammonium sulfate
Pressure: 755 Torr
Individual Files - View, select, and download individual files from this Dataset.
Zip File - Download a ZIP file containing all files.
Python script - Download all files via Python 3, preferred for all operating systems.
Wget shell script - Download all files using Wget, preferred for Linux.
Curl shell script - Download all files via Curl, preferred for MacOS.