Aug 23, 2023

ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20150130_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_Ammonium sulfate_RH40%

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Version: 20230823-020154

Goals:
This experiment was done to study the Methacrolein high NO2 photoxidation in the presence of wet ammonium sulfate (AS) seeds at RH 40%, since the other experiments were done at low RH and without seed particles. The hypothesis is that particle liquid water will decrease SOA formation because water will hydrolyze HMML instead of allowing it to oligomerize on the particle surface. This liquid water is also hypothesized to liberate 2-methylgycleric acid (2MGA) from the aerosol to the gas phase.

Summary:
Interestingly, gas-phase 2MGA is not significantly enhanced and aerosol mass is not significantly decreased in the 40% RH experiment (Exp. #12) compared to the dry experiments. It is possible that the liquid water content under these conditions (?30 vol%) is not high enough to dominate the reaction with HMML or there is a barrier to 2MGA volatilization. We do see the hypothesis confirmed in the fully deliquesced particle in the 85% RH experiment (150208)

Organization: Caltech Atmospheric Chamber
Lab Affiliation: California Institute of Technology, Pasadena, CA
Chamber: Near/Far Bag 2012-2015 (Tran)

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Hydroxyl radical
Reactants: METHACROLEIN, Methyl nitrite, 10102-44-0
Reaction Type: Photooxidation
Relative Humidity: 40
Temperature: 25
Seed Name: Ammonium sulfate
Pressure: 750 Torr

DOI: https://doi.org/10.5065/b9xa-zt95

ICARUS Experiment Details: https://icarus.ucdavis.edu/experiment/621

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Temporal Range: 2015-01-30 to 2015-01-30

Related Links: Publication - Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere

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Support Contact

Kong, Stephanie
Caltech Atmospheric Chamber
wkong@caltech.edu

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints: Creative Commons Attribution 4.0 International License.

Access Constraints: These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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Authors: Seinfeld, John

Publisher

ICARUS Community

Suggested Citation: Seinfeld, John. (2023). ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20150130_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_Ammonium sulfate_RH40%. Version 20230823-020154. ICARUS Community. https://doi.org/10.5065/b9xa-zt95. Accessed 25 Jan 2025.

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