ICARUS Chamber Experiment: Nguyen Group_20190814_ALPHA-PINENE/OZONE/10102-44-0/hydrogen peroxide_Nitrate radical_Ammonium sulfate

Goals:
To quantify the nitrooxy-hydroperoxide yield and the SOA yield from nighttime RO2+HO2-dominated NO3-initiated chemistry of a-pinene by adding H2O2 + ozone + NO2 to the chamber. Part of a series of varying initial reactant concentrations slightly to target different chemical pathways. This one targeted high initial NO3 by adding more O3 and NO2 and a higher NO2/O3 ratio.

Summary:
H2O2, NO2, and O3 were injected in the chamber and allowed to equilibrate, forming NO3 (and some N2O5) and probably HO2. Ammonium sulfate seed particles were injected. Then a-pinene was injected and decayed by simultaneous reaction with ozone and NO3. Gas phase was monitored by CF3O- CIMS and particle formation by SMPS.

Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Nitrate radical
Reactants: ALPHA-PINENE, OZONE, 10102-44-0, hydrogen peroxide
Reaction Type: Dark oxidation
Relative Humidity: 5
Temperature: 22
Seed Name: Ammonium sulfate
Pressure: 755 Torr

DOI

https://doi.org/10.5065/7bsh-0g42

ICARUS Experiment Details

https://icarus.ucdavis.edu/experiment/571

Temporal Range

2019-08-14 to 2019-08-14

Related Links

N/A

GCMD Science Keywords

• Atmosphere > Aerosols
• Atmosphere > Atmospheric Chemistry > Trace Gases/Trace Species

GCMD Instruments

• In Situ/Laboratory Instruments > Chemical Meters/Analyzers

File Media Types

• application/zip

Support Contact

Bates, Kelvin
Nguyen Group
kelvinhbates@gmail.com

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints

Creative Commons Attribution 4.0 International License.

Access Constraints

These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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