Aug 23, 2023

ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180115_octane/nitric oxide/nitrite_Chlorine radical_Ammonium sulfate_medRH

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Version: 20230823-015157

Goals:
Find SOA yield for octane + Cl under high NOx condition (NO and NO2 injected) at RH=35%. Investigate volatility behavior based on 2D thermograms.

Summary:
Ammonium sulfate seed (0.01M, 150 mL) was injected using an aerosol generation system. Cl2 gas, NO and NO2 gas were injected from their cylinders. 1 uL of octane was injected into a glass bulb and heated clean air was made to flow over it, carrying the volatilized octane into the chamber. After ~30 mins (sufficient mixing time), lights were turned on for 1 hour (14:47:52-15:48:00). 16.8 ug/m3 of SOA was formed, giving a mass yield of 0.24. This is Exp#4 in associated publication.

Organization: Hildebrandt Ruiz Lab
Lab Affiliation: University of Texas at Austin, Austin, TX, USA
Chamber: LHR Chamber

Experiment Category: Gas phase chemical reaction, Volatility and partitioning, Aerosol formation
Oxidant: Chlorine radical
Reactants: octane, nitric oxide, nitrite
Reaction Type: Photooxidation
Relative Humidity: 35
Temperature: 25
Seed Name: Ammonium sulfate

DOI: https://doi.org/10.5065/dmfr-2w51

ICARUS Experiment Details: https://icarus.ucdavis.edu/experiment/204

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Temporal Range: 2018-01-15 to 2018-01-15

Related Links: Publication - Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO?CIMS

GCMD Science Keywords

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Support Contact

Hildebrandt Ruiz, Lea
Hildebrandt Ruiz Lab
lhr@che.utexas.edu

Data Curator

GDEX Curator
UCAR/NCAR - GDEX
gdex@ucar.edu

Legal Constraints: Creative Commons Attribution 4.0 International License.

Access Constraints: These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.

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Authors: Hildebrandt Ruiz, Lea

Publisher

ICARUS Community

Suggested Citation: Hildebrandt Ruiz, Lea. (2023). ICARUS Chamber Experiment: Hildebrandt Ruiz Lab_20180115_octane/nitric oxide/nitrite_Chlorine radical_Ammonium sulfate_medRH. Version 20230823-015157. ICARUS Community. https://doi.org/10.5065/dmfr-2w51. Accessed 27 Nov 2024.

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