Title:

ICARUS Chamber Experiment: Jimenez Lab_20160816_1-octanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_18.6_ug/m3_AS3


Description:

Goals:
Fast burst photooxidation of alkanols (high-NOx). Gas-aerosol-wall partitioning kinetics. Determine accommodation coefficient (alpha) and effective volatility under differing seed aerosol types (differing phase and polarities, inorganic/organic, humid/dry, standards/SOA).

Summary:
Alkanols, Methyl nitrite, NO, and particle seed added to chamber, UV lights turned on for 10 sec, multifunctional products formed. In most experiments in this experimental set, 10-s UV light/photochemistry burst repeated a few times. SMPS measurements of particle size distributions were conducted to determine particle formation, surface area and condensational sink rate coefficients. 
Gas-phase chemical species were measured with nitrate CIMS.

Organization: Jimenez Lab
Lab Affiliation: University of Colorado, Boulder
Chamber: 1-White (1W)

Experiment Category: Volatility and partitioning
Oxidant: Hydroxyl radical
Reactants: 1-octanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL
Reaction Type: Photooxidation
Relative Humidity: <1
Temperature: 25
Seed Name: Ammonium sulfate


Metadata URL:

https://gdex.ucar.edu/dataset/id/b0f06807-69c8-4223-b874-0ec4e201db0a.html